Seasonal changes in the PM1 chemical composition north of Mexico City

Franco Guerrero, Harry Alvarez-Ospina, Armando Retama, Alfonso López-Medina, Telma Castro, Dara Salcedo

Abstract


An Aerodyne Aerosol Chemical Speciation Monitor (ACSM; Aerodyne Inc.) was deployed at a site north of Mexico City from November 13, 2013 to April 30, 2014 to investigate the seasonal variability of the chemical composition of submicron particles. The ACSM provides real time information on mass concentration of the non-refractory main species (nitrate, sulfate, ammonium, chloride and organic compounds) in particulate matter less than 1 μm (NR-PM1) with a 30-min time resolution. Meteorological variables (temperature, relative humidity, and wind speed and direction), as well as concentrations of black carbon, PM1, PM2.5, CO, SO2, NO, NO2, and O3, were also measured. The total NR-PM1 mass concentrations plus black carbon (which must be close to the PM1 total mass) showed a good correlation with PM1 mass concentration measured with a Tapered Element Oscillating Micro-Balance, an indication of the soundness of the ACSM data. In average, the composition of the aerosol as well as its diurnal variability were similar to observations in previous studies using  similar instruments (MCMA-2003 and MILAGRO). However, it was observed that the aerosol was persistently acidic during November and December probably due to a higher relative humidity, lower temperature, and more frequent winds from the NW, where the Tula industrial complex is located. A lower concentration of ammonia (NH3) in the gas phase might affect the PM acidity too. These results suggest a seasonal variability in the aerosol chemistry in Mexico City, which should be verified with more long-term studies.


Keywords


ACSM; NR-PM1 chemical composition; aerosol acidity; Mexico City

Full Text:

PDF


DOI: http://dx.doi.org/10.20937/ATM.2017.30.03.05

Copyright (c) 2017 Atmósfera

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Atmósfera, vol. 30, issue 3, July-September 2017, is a quarterly journal published by the Universidad Nacional Autónoma de México via the Centro de Ciencias de la Atmósfera, Circuito de la Investigación Científica s/n, Ciudad Universitaria, Delegación Coyoacán, 04510 CDMX, phone number (+52 55) 5622-4240, ext. 81888, http://www.revistascca.unam.mx/atm, editor@atmosfera.unam.mx. Editor in Chief: Jorge Zavala Hidalgo. ISSN 2395-8812. Person in charge of the last update of this issue: Claudio Mario Amescua García, Editorial Office of the Centro de Ciencias de la Atmósfera. Last modification: July 1, 2017.

The views expressed by the authors do not necessarily reflect the viewpoint of the Editor or the publisher. Reproduction of this work (or sections thereof) for non-commercial purposes is permited, provided the source is provided and acknowledged.